New climate data records of ozone and aerosol precursor gases

2023-2024
As part of ESA’s Climate Change Initiative programme, BIRA-IASB is leading a new project aiming to develop harmonised long-term data records of six atmospheric trace gases (NO2, HCHO, SO2, CHOCHO, CO and NH3) that are precursors of ozone and aerosol Essential Climate Variables (ECVs).

The development of HCHO, SO2 and CHOCHO products as well as the overall validation activities are under BIRA-IASB responsibility. Our tropospheric modelling team also performs an in-depth assessment, demonstrating the value of the new data for climate studies.

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ESA Climate Change Initiative (CCI) for Aerosol and Ozone Essential Climate Variables

Tropospheric ozone (O₃) trends are nonlinearly influenced by near-surface anthropogenic emissions of carbon monoxide (CO), volatile organic compounds (VOCs), and nitrogen oxides (NOₓ).

As part of its Climate Change Initiative (CCI) programme, the European Space Agency (ESA) recently launched a project coordinated at BIRA-IASB, aiming to generate robust, long-term records of key short-lived atmospheric species, precursors of ozone and aerosol particles.

Six species are under focus:

  • NO2
  • HCHO
  • SO2 
  • CHOCHO
  • CO
  • NH3 

By integrating data from multiple satellite missions—including GOME, SCIAMACHY, OMI, and TROPOMI— harmonized and consistent Climate Data Records (CDRs) of HCHO and NO2 spanning more than two decades are being produced. Significant improvements in retrieval algorithms have enhanced the accuracy, precision, and the long-term stability of the data sets.

Validation against ground-based measurements from FTIR and MAX-DOAS demonstrates reduced biases in HCHO observations, resulting in more reliable data for climate monitoring and trend analysis.

Trends analysis over 15 years

The figures llustrate trend analyses based on the recently produced HCHO and NO₂ CCI CDRs, derived from OMI and TROPOMI measurements.

Average column HCHO (2005-2023)
Formaldehyde (HCHO) data developed as part of the ESA CCI+ Precursors for Aerosol and Ozone ECV. The average columns [1015molec.cm-2] derived from OMI and TROPOMI are shown for HCHO (2005-2023).
HCHO trend
Corresponding trends [1015molec.cm-2yr-1].

Notable regional trends emerge, with southern Asia—particularly India—exhibiting the most pronounced increases in HCHO. Central Africa, parts of central Brazil, and northern Australia also show rising trends. In contrast, HCHO levels have declined in the southeastern United States, Europe, eastern Asia, and southern Australia.

For NO₂, decreasing trends are observed in western and southern Europe, North America, Japan, and Indonesia. Certain eastern regions of China also show declines, though other areas continue to experience rising NO₂ levels. India, southeastern Asia, and parts of the Middle East display increasing NO₂ trends.

NO2 average column
Nitrogen dioxide (NO2) data developed as part of the ESA CCI+ Precursors for Aerosol and Ozone ECV. The average columns [1015molec.cm-2] derived from OMI and TROPOMI are shown for NO2 (2005-2021). 
NO2 trend
Corresponding trends [1015molec.cm-2yr-1].

The observed decreases in surface ozone over the northeastern United States and Europe are attributed to simultaneous reductions in NO₂ and HCHO, a result of effective air pollution mitigation policies implemented over the past two decades [Elshorbany et al., 2024, Fadnavis et al., 2024].

The CCI data is provided in user-friendly formats that optimize download efficiency, ensuring accessibility without requiring large file transfers. This streamlined distribution enhances usability, making these critical climate datasets widely available for climate and atmospheric research.

Links

References

  • Elshorbany, Y., Ziemke, J., Strode, S., Petetin, H., Miyazaki, K., De Smedt, I., Pickering, K., Seguel, R., Worden, H., Emmerichs, T., Taraborrelli, D., Cazorla, M., Fadnavis, S., Buchholz, R., Gaubert, B., Rojas, N., Nogueira, T., Salameh, T., and Huang, M.: Tropospheric Ozone Precursors: Global and Regional Distributions, Trends and Variability, EGUsphere [preprint], https://doi.org/10.5194/egusphere-2024-720, 2024.
     
  • Fadnavis, S., Elshorbany, Y., Ziemke, J., Barret, B., Rap, A., Chandran, P. R. S., Pope, R., Sagar, V., Taraborrelli, D., Le Flochmoen, E., Cuesta, J., Wespes, C., Boersma, F., Glissenaar, I., De Smedt, I., Van Roozendael, M., Petetin, H., and Anglou, I.: Influence of nitrogen oxides and volatile organic compounds emission changes on tropospheric ozone variability, trends and radiative effect, EGUsphere [preprint], https://doi.org/10.5194/egusphere-2024-3050, 2024.

 

Figure 2 body text

Figure 2 caption (legend)

Formaldehyde (HCHO) data developed as part of the ESA CCI+ Precursors for Aerosol and Ozone ECV. Example of HCHO Climate Data Record (CDR) and calculated trends over the Indian region.

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Figure 3 caption (legend)

Nitrogen dioxide (NO2) data developed as part of the ESA CCI+ Precursors for Aerosol and Ozone ECV. Example of NO2 Climate Data Record (CDR) and calculated trends over the Indian region.